Fictional villains thought to be good at first but then reveal to be bad
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Stewie Griffin (character) -
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- Sailor John
- Salazar's Dogs (Animaniacs)
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- Sasuke Uchiha (character)
- Scarlett (Total Drama)
- Scorpan
- Scout Master Lumpus
- Shadow the Hedgehog (character)
- Sheldon J. Plankton (character)
- Shredder (character)
- Sigma (Mega Man X)
- Snow White (Animaniacs)
- Sour Bill
- Sterling (Cars)
- Stewie Griffin (character)
- Stinger
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- Stromboli
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