Sonic/Super Smash Bros. Brawl: Classic Mode

Normal Battle

 * Espio as Link
 * Blaze as Zelda
 * Rouge as Sheik
 * Snively as Ganondorf
 * E-102 Gamma as Toon Link
 * Tails as Yoshi
 * Vector as Donkey Kong
 * Charmy as Diddy Kong
 * Classic Sonic as Pikachu
 * Classic Amy as Jigglypuff
 * Classic Tails as Pokemon Trainer
 * Bokkun as Squirtle
 * Bocoe as Ivysaur
 * Decoe as Charizard
 * Classic Knuckles as Lucario
 * Heavy as Marth
 * Bomb as Ike
 * Rotor as Ness
 * Rocket as Lucas
 * Chris as Kirby
 * Dr. Warpnik as King Dedede
 * Cluck as Meta Knight
 * Cream as Samus
 * Cosmo as Zero Suit Samus
 * Robotnik Jr. as Olimar
 * Mighty as Fox
 * Ray as Falco
 * Scourge as Wolf
 * Big as Captain Falcon
 * Sonic as Mario
 * Knuckles as Luigi
 * Amy as Peach
 * Dr. Eggman as Bowser
 * Chip as Mr. Game & Watch
 * Danny as Pit
 * Manic and Sonia as Ice Climbers
 * Metal Sonic as R.O.B.
 * Shadow as Wario
 * E-123 Omega as Snake
 * Silver as Sonic

Multi-Man Battle

 * Espio and Blaze as Link and Zelda
 * Espio and Rouge as Link and Sheik
 * Espio and Snively as Link and Ganondorf
 * Espio and E-102 Gamma as Link and Toon Link
 * Blaze and Snively as Zelda and Ganondorf
 * Blaze and E-102 Gamma as Zelda and Toon Link
 * Rouge and Snively as Sheik and Ganondorf
 * Rouge and E-102 Gamma as Sheik and Toon Link
 * Snively as E-102 Gamma as Ganondorf and Toon Link
 * Charmy and Vector as Diddy Kong and Donkey Kong
 * Classic Sonic and Bokkun as Pikachu and Squirtle
 * Classic Sonic and Bocoe as Pikachu and Ivysaur
 * Classic Sonic and Decoe as Pikachu and Charizard
 * Classic Sonic and Classic Knuckles as Pikachu and Lucario
 * Classic Sonic and Classic Amy as Pikachu and Jigglypuff
 * Bokkun and Classic Knuckles as Squirtle and Lucario
 * Bocoe and Classic Knuckles as Ivysaur and Lucario
 * Decoe and Classic Knuckles as Charizard and Lucario
 * Bokkun and Classic Amy as Squirtle and Jigglypuff
 * Bocoe and Classic Amy as Ivysaur and Jigglypuff
 * Decoe and Classic Amy as Charizard and Jigglypuff
 * Classic Knuckles and Classic Amy as Lucario and Jigglypuff
 * Heavy and Bomb as Marth and Ike
 * Rotor and Rocket as Ness and Lucas
 * Chris and Cluck as Kirby and Meta Knight
 * Chris and Dr. Warpnik as Kirby and King Dedede
 * Cluck and Dr. Warpnik as Meta Knight and King Dedede
 * Mighty and Ray as Fox and Falco
 * Mighty and Scourge as Fox and Wolf
 * Scourge and Ray as Wolf and Falco
 * Sonic and Knuckles as Mario and Luigi
 * Sonic and Amy as Mario and Peach
 * Sonic and Dr. Eggman as Mario and Bowser
 * Knuckles and Amy as Luigi and Peach
 * Knuckles and Dr. Eggman as Luigi and Bowser
 * Dr. Eggman and Amy as Bowser and Peach

Giant Battle

 * Giant Tails as Giant Yoshi
 * Giant Classic Sonic as Giant Pikachu
 * Giant Bokkun as Giant Squirtle
 * Giant Bocoe as Giant Ivysaur
 * Giant Decoe as Giant Charizard
 * Giant Classic Knuckles as Giant Lucario
 * Giant Classic Amy as Giant Jigglypuff
 * Giant Heavy as Giant Marth
 * Giant Bomb as Giant Ike
 * Giant Rotor as Giant Ness
 * Giant Rocket as Giant Lucas
 * Giant Chris as Giant Kirby
 * Giant Dr. Warpnik as Giant King Dedede
 * Giant Cluck as Giant Meta Knight
 * Giant Cream as Giant Samus
 * Giant Cosmo as Giant Zero Suit Samus
 * Giant Robotnik Jr. as Giant Olimar
 * Giant Mighty as Giant Fox
 * Giant Ray as Giant Falco
 * Giant Scourge as Giant Wolf
 * Giant Big as Giant Captain Falcon
 * Giant Sonic as Giant Mario
 * Giant Knuckles as Giant Luigi
 * Giant Amy as Giant Peach
 * Giant Dr. Eggman as Giant Bowser
 * Giant Chip as Giant Mr. Game & Watch
 * Giant Danny as Giant Pit
 * Giant Manic and Sonia as Giant Ice Climbers
 * Giant Shadow as Giant Wario
 * Giant E-123 Omega as Giant Snake
 * Giant Silver as Giant Sonic

Team Battle

 * Team Heavy as Team Marth
 * Team Bomb as Team Ike
 * Team Rotor as Team Ness
 * Team Rocket as Team Lucas
 * Team Chris as Team Kirby
 * Team Dr. Warpnik as Team King Dedede
 * Team Cluck as Team Meta Knight
 * Team Cream as Team Samus
 * Team Cosmo as Team Zero Suit Samus
 * Team Robotnik Jr. as Team Olimar
 * Team Mighty as Team Fox
 * Team Ray as Team Falco
 * Team Scourge as Team Wolf
 * Team Big as Team Captain Falcon
 * Team Sonic as Team Mario
 * Team Knuckles as Team Luigi
 * Team Amy as Team Peach
 * Team Dr. Eggman as Team Bowser
 * Team Chip as Team Mr. Game & Watch
 * Team Danny as Team Pit
 * Team Manic and Sonia as Team Ice Climbers
 * Team Metal Sonic as Team R.O.B.
 * Team Shadow as Team Wario
 * Team E-123 Omega as Team Snake
 * Team Silver as Team Sonic

Metal Battle

 * Metal Cream as Metal Samus
 * Metal Cosmo as Metal Zero Suit Samus
 * Metal Robotnik Jr. as Metal Olimar
 * Metal Mighty as Metal Fox
 * Metal Ray as Metal Falco
 * Metal Scourge as Metal Wolf
 * Metal Big as Metal Captain Falcon
 * Metal Sonic as Metal Mario
 * Metal Knuckles as Metal Luigi
 * Metal Amy as Metal Peach
 * Metal Dr. Eggman as Metal Bowser
 * Metal Chip as Metal Mr. Game & Watch
 * Metal Danny as Metal Pit
 * Metal Manic and Sonia as Metal Ice Climbers
 * Metal Metal Sonic as Metal R.O.B.
 * Metal Shadow as Metal Wario
 * Metal E-123 Omega as Metal Snake
 * Metal Silver as Metal Sonic

Free for All Battle

 * Sonic as Mario
 * Knuckles as Luigi
 * Amy as Peach
 * Dr. Eggman as Bowser
 * Vector as Donkey Kong
 * Charmy as Diddy Kong
 * Tails as Yoshi
 * Shadow as Wario
 * Espio as Link
 * Blaze as Zelda
 * Snively as Ganondorf
 * E-102 Gamma as Toon Link
 * Cream as Samus
 * Danny as Pit
 * Manic and Sonia as Ice Climbers
 * Metal Sonic as R.O.B.
 * Chris as Kirby
 * Cluck as Meta Knight
 * Dr. Warpnik as King Dedede
 * Robotnik Jr. as Olimar
 * Mighty as Fox
 * Ray as Falco
 * Scourge as Wolf
 * Big as Captain Falcon
 * Classic Sonic as Pikachu
 * Classic Tails as Pokemon Trainer
 * Decoe as Charizard
 * Classic Knuckles as Lucario
 * Classic Amy as Jigglypuff
 * Heavy as Marth
 * Bomb as Ike
 * Rotor as Ness
 * Rocket as Lucas
 * Chip as Mr. Game & Watch
 * E-123 Omega as Snake
 * Silver as Sonic

Final Battle

 * Sleet and Dingo as Master Hand and Crazy Hand